HYDRIDE TO CARBENE MIGRATION AT MOLYBDENUM - THE ISOMERIZATION OF MO(H)(=C[CH2]3NME)(CO)2(ETA-C5H5) TO "MO(CO)2(ETA2-CH[CH2]3NME)(ETA-C5H5)

被引：43

作者：

OSBORN, VA ^{[1
]}

PARKER, CA ^{[1
]}

WINTER, MJ ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1986年 / 15期

关键词：

D O I：

10.1039/c39860001185

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1185 / 1186

页数：2

共 17 条

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[12] CYCLIC CARBENE COMPLEXES OF THE TYPE CIS-MI[CN(ME)(CH2)NCH2](CO)2(ETA-C5H5) (M = MO, N = 2 OR 3, M = W, N = 2) - THEIR SYNTHESES AND REACTIONS OF THE MOLYBDENUM SYSTEMS WITH LIET3BH
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[13] SYNTHESIS OF ANIONIC MOLYBDENUM AND TUNGSTEN CARBENE COMPLEXES OF THE TYPE [M(CARBENE)(CO)2(ETA-C5H5)]-(M = MO OR W) BY THE SODIUM NAPHTHALIDE REDUCTION OF IODO CARBENE COMPLEXES
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (24) : 1744 - 1745
[14] EVIDENCE FOR REVERSIBLE ALPHA-HYDROGEN ABSTRACTION FROM METHYLCOBALT AND METHYLRHODIUM COMPLEXES INVOLVING POSSIBLE FORMATION OF HYDRIDO-CARBENE INTERMEDIATES
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (01) : 9 - 10
[15] MIGRATORY INSERTION REACTIONS OF CARBENES - KINETICS AND MECHANISM OF MIGRATORY INSERTION REACTIONS OF ZIRCONOXY CARBENE COMPLEXES OF NIOBOCENE HYDRIDE AND ALKYLS
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (10) : 2650 - 2659
[16] MIGRATORY APTITUDE OF HYDRIDE AND METHYL TOWARD CARBON-MONOXIDE, THIOCARBONYL, AND CARBENE IN RMN(CO)4XY (XY = CO, CS, CH2 - R = H, CH3) - A THEORETICAL-STUDY BY THE HARTREE-FOCK-SLATER TRANSITION-STATE METHOD
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (04) : 612 - 617
[17] [No title captured]

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