TRANSALKYLATION APPLIED TO THE STRUCTURAL CHARACTERIZATION OF KEROGENS

被引：6

作者：

BAUDET, N ^{[1
]}

AMBLES, A ^{[1
]}

JACQUESY, JC ^{[1
]}

VANDENBROUCKE, M ^{[1
]}

BEHAR, F ^{[1
]}

机构：

[1] INST FRANCAIS PETR,F-92506 RUEIL MALMAISON,FRANCE

来源：

FUEL | 1994年 / 73卷 / 10期

关键词：

KEROGEN; MOLECULAR STRUCTURE; TRANSALKYLATION;

D O I：

10.1016/0016-2361(94)90137-6

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Spectroscopic measurements give only general information about the presence of aromatics and alkyl groups in kerogens. To obtain more specific details about the substitution of the aromatics by alkyl chains, transalkylation was applied to type II kerogens (Timahdit-Y and Tarfaya from Morocco, and Donnemarie from the Paris Basin) using CF3SO3H and benzene. Many products were obtained, including homologous series of phenylalkanes, 1,1-diphenylalkanes, alkylteteralins and alkylnaphthalenes. As the latter are secondary products from alkylbenzenes, the distribution of alkyl substituents of the aromatics in kerogen was determined. The transfer was evaluated by a study of the pyrolysis of the initial and transalkylated kerogens.

引用

页码：1594 / 1599

页数：6

共 21 条

[1] CHEMICAL CHARACTERIZATION OF OIL-SHALE KEROGENS USING A TRANSALKYLATION REACTION [J].