A LOW-VALENCE COBALT CLUSTER FORMED VIA CAPTURE OF SULFUR ATOM FROM ETHANEDITHIOL - SYNTHESIS AND CRYSTAL-STRUCTURE OF [CO7(MU-4-S)3(MU-3-S)3(PPH3)6BR].CH3OH

被引：9

作者：

JIANG, FL ^{[1
]}

LEI, XJ ^{[1
]}

HONG, MC ^{[1
]}

HUANG, ZY ^{[1
]}

KANG, BS ^{[1
]}

LIU, HQ ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUZHOU 350002,PEOPLES R CHINA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 443卷 / 02期

关键词：

D O I：

10.1016/0022-328X(93)80301-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The low-valence cobalt cluster [Co7(mu4-S)3(mu3-S)3(PPh3)6Br] (1) was isolated from the reaction of Co(PPh3)3Br with Na2edt in ethylene chloride. The skeleton [Co7S6]+ of 1 can be represented as a monocapped-prismane formed by the addition of the capping atom cobalt to the prismane [Co6S6] as shown by X-ray single-crystal structure analysis. In this reaction the S2- ion is derived from the edt2- ion through cleavage of the C-S bond, and incorporated into the building process.

引用

页码：229 / 231

页数：3

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