ELECTRON-TRANSFER REACTIONS OF GEMINATE PAIRS AT HIGH EXERGONICITIES

被引：8

作者：

ZALESKI, JM ^{[1
]}

TURRO, C ^{[1
]}

MUSSELL, RD ^{[1
]}

NOCERA, DG ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,LASER LAB,E LANSING,MI 48824

来源：

COORDINATION CHEMISTRY REVIEWS | 1994年 / 132卷

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0010-8545(94)80048-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three systems have been designed to study the roles of driving force, distance, and static and dynamics solvent effects on the rates of electron transfer (ET) reactions of geminate pairs at high exergonicities. The bimolecular ET reaction of electrogenerated geminate pairs, and the unimolecular ET reactions of covalently tethered geminate pairs, and geminate pairs juxtaposed by a hydrogen-bonded interface are described.

引用

页码：249 / 258

页数：10

共 44 条

[41] DYNAMIC SOLVENT EFFECTS ON ACTIVATED ELECTRON-TRANSFER REACTIONS - PRINCIPLES, PITFALLS, AND PROGRESS [J].