REMARKABLE STEREOCHEMICAL INVERSION IN SOME HECK ARYLATION REACTIONS - A MECHANISTIC PROPOSAL

被引:13
作者
MCCLURE, KF [1 ]
DANISHEFSKY, SJ [1 ]
SCHULTE, GK [1 ]
机构
[1] YALE UNIV,CTR CHEM INSTRUMENTAT,NEW HAVEN,CT 06511
关键词
D O I
10.1021/jo00081a012
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Internal arylation reactions of enol ethers were used to form the 1,5-epoxybenzazocine ring system of FR 900482. An interesting inversion process was observed for Z-enol ethers.
引用
收藏
页码:355 / 360
页数:6
相关论文
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