SYNTHESES OF 2,9-BIS(HALOMETHYL)-1,10-PHENANTHROLINES - POTENTIAL ROBUST LIGANDS FOR METAL OXIDATION CATALYSTS

被引：33

作者：

BEER, RH ^{[1
]}

JIMENEZ, J ^{[1
]}

DRAGO, RS ^{[1
]}

机构：

[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 07期

关键词：

D O I：

10.1021/jo00059a024

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Free radical halogenation of 2,9-dimethyl-1,10-phenanthroline with N-bromosuccinimide and N-chlorosuccinimide form the known alpha-methyl derivatives 2,9-bis(trihalomethyl)-1,10-phenanthrolines. The compound 2,9-bis(trichloromethyl)-1,10-phenanthroline can be used for one-step syntheses of oxidatively resistant fluoro- and partially reduced chloromethyl derivatives capable of coordination to metal oxidation catalysts.

引用

页码：1746 / 1747

页数：2

共 15 条

[1] CHANDLER CJ, 1982, J HETEROCYCLIC CHEM, V19, P599
[2] STABLE HIGHLY OXIDIZING COBALT COMPLEXES OF MACROCYCLIC LIGANDS
COLLINS, TJ
POWELL, RD
SLEBODNICK, C
UFFELMAN, ES
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (22) : 8419 - 8425
[3] GOLDSTEIN A, UNPUB
[4] GOLDSTEIN AS, 1991, J CHEM SOC CHEM COMM, P22
[5] Hudlicky M., 1976, CHEM ORGANIC FLUORIN
[6] LEUNG WH, 1988, J CHEM SOC CHEM COMM, P1406
[7] SELECTIVE LOW-TEMPERATURE HYDROXYLATION OF ISOBUTANE BY MOLECULAR-OXYGEN CATALYZED BY AN IRON PERHALOPORPHYRIN COMPLEX
LYONS, JE
ELLIS, PE
[J]. CATALYSIS LETTERS, 1991, 8 (01) : 45 - 51
[8] LYONS JE, 1900, J CATAL LETT, V29, P1028
[9] ALPHA-METHYL FUNCTIONALIZATION OF ELECTRON-POOR HETEROCYCLES - 2,9-BIS(CHLOROMETHYL)-1,10-PHENANTHROLINE - SYNTHESIS OF A [3.3)CYCLOPHANE CONTAINING THE 1,10-PHENANTHROLINO MOIETY
NEWKOME, GR
KIEFER, GE
PUCKETT, WE
VREELAND, T
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (25) : 5112 - 5114
[10] CHEMISTRY OF HETEROCYCLIC-COMPOUNDS .124. MONO-ALPHA-FUNCTIONALIZATION OF 2,9-DIMETHYL-1,10-PHENANTHROLINE
NEWKOME, GR
THERIOT, KJ
GUPTA, VK
FRONCZEK, FR
BAKER, GR
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (07) : 1766 - 1769

← 1 2 →