ACCELERATION OF A DIPOLAR CLAISEN REARRANGEMENT BY HYDROGEN-BONDING TO A SOLUBLE DIARYL UREA

被引：40

作者：

CURRAN, DP

KUO, LH

机构：

[1] Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 37期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/00404-0399(50)1394-W

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Claisen rearrangement of 6-methoxy allyl vinyl ether is catalyzed by a soluble diaryl urea, and evidence is presented that the urea stabilizes a dipolar transition state by hydrogen bonding.

引用

页码：6647 / 6650

页数：4

共 17 条

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