PSEUDO-CATIONIC TRIFLUOROMETHYLATION OF ENOL ESTERS WITH SODIUM TRIFLUOROMETHANESULFINATE

被引:106
作者
LANGLOIS, BR
LAURENT, E
ROIDOT, N
机构
[1] Lab. de Chimie Organique 3, associé au C.N.R.S., Université Claude Bernard, F 69622 Villeurbanne, 43 Bd du
关键词
TRIFLUOROMETHYLATION; ENOL ESTERS; SODIUM TRIFLUOROMETHANESULFINATE; T-BUTYL HYDROPEROXIDE; COPPER(II) CATALYST;
D O I
10.1016/S0040-4039(00)91604-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Enol esters are converted into corresponding trifluoromethylated ketones and/or enol esters with sodium trifluoromethanesulfinate and t-butyl hydroperoxide in the presence of catalytic amounts of Cu(II).
引用
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页码:1291 / 1294
页数:4
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