SILYLAMINES WITH PYRAMIDAL COORDINATION AT NITROGEN

被引：50

作者：

RUHLANDTSENGE, K ^{[1
]}

BARTLETT, RA ^{[1
]}

OLMSTEAD, MM ^{[1
]}

POWER, PP ^{[1
]}

机构：

[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 03期

关键词：

D O I：

10.1002/anie.199304251

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The pi component of the Si-N bond in silylamines has little if any influence on their structure--this was established from the X-rav structures of the silylamines 1-3. The structural analyses show that the coordination at the nitrogen centers is pyramidal rather than planar and that the Si-N distances are essentially invariant. Mes = 2,4,6-Me3C6H2. Triph = 2,4.6-Ph3C6H2. [GRAPHICS]

引用

页码：425 / 427

页数：3

共 26 条

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