CONVENIENT SYNTHESIS OF THE 1,4-BISHOMO-6-SECOHEPTAPRISMANE RING-SYSTEM

被引：33

作者：

FORMAN, MA ^{[1
]}

DAILEY, WP ^{[1
]}

机构：

[1] UNIV PENN,DEPT CHEM,PHILADELPHIA,PA 19104

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 06期

关键词：

D O I：

10.1021/jo00058a035

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The facile synthesis of 13, a highly functionalized 1,4-bishomo-6-secoheptaprismane, is reported in 45% overall yield, starting with the Diels-Alder adduct of 5,5-dimethoxy-1,2,3,4-tetrachlorocyclopentadiene and p-benzoquinone. Initial attempts to functionalize 13 for subsequent transformation to hexaprismane (1) are summarized.

引用

页码：1501 / 1507

页数：7