ON THE BEHAVIOR OF NITROGEN-OXIDES IN LIQUEFIED ARGON AND KRYPTON - DIMERIZATION OF NITRIC-OXIDE

被引：15

作者：

SLUYTS, EJ ^{[1
]}

VANDERVEKEN, BJ ^{[1
]}

机构：

[1] UNIV CTR ANTWERPEN,DEPT CHEM,GROENENBORGERLAAN 171,B-2020 ANTWERP,BELGIUM

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1994年 / 320卷

关键词：

D O I：

10.1016/0022-2860(94)07975-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solutions containing several nitrogen oxide species have been investigated in liquefied argon in the temperature range 84-105 K, and in liquefied krypton in the temperature range 116-150 K, using infrared spectroscopy. The following nitrogen oxide species were characterised in these solutions: NO, cis-ONNO, trans-ONNO, the asymmetric dimer ONON, asymmetric ONNO2, Symmetric ONONO and N2O4 with D2h symmetry. The enthalpy of dimerisation of NO to cis-ONNO has been determined in liquefied argon to be -14.3 +/- 1 kJ mol-1.

引用

页码：249 / 267

页数：19

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