MICHAEL ADDITION OF FORMALDEHYDE DIMETHYLHYDRAZONE TO NITROOLEFINS - A NEW FORMYL ANION EQUIVALENT

被引：39

作者：

LASSALETTA, JM

FERNANDEZ, R

机构：

[1] Departamento de Química Orgánica, Universidad de Sevilla, E-41071 Seville

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 25期

关键词：

FORMYL ANION EQUIVALENT; N; N-DIALKYLHYDRAZONES; NITROOLEFINS; MICHAEL REACTION; BETA-NITROALDEHYDES;

D O I：

10.1016/S0040-4039(00)92538-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Formaldehyde dimethylhydrazone readily adds to simple nitro-olefins in the absence of base giving beta-nitrodimethylhydrazones in very high yields. The corresponding beta-nitroaldehydes cam be obtained by ozonolysis.

引用

页码：3691 / 3694

页数：4

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