CATIONIC CARBON TO NITROGEN REARRANGEMENTS IN THE REACTIONS OF N-(SULFONYLOXY)AMINES WITH ALDEHYDES

被引：12

作者：

HOFFMAN, RV

SALVADOR, JM

机构：

[1] Department of Chemistry, New Mexico State University, Las Cruces

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 16期

关键词：

D O I：

10.1021/jo00042a032

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of aromatic and aliphatic aldehydes was reacted with N-((p-nitrobenzenesulfonyl)oxy)methylamine in chloroform. Products resulting from both carbon migration and hydride migration to nitrogen were isolated. The ratios of carbon to hydride migration products were used to clarify the reaction mechanism. The results support a two-step process in which cationic carbon to nitrogen rearrangement is rate determining.

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页码：4487 / 4490

页数：4

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