COUPLING OF A 17-ELECTRON VINYL COMPLEX WITH CHIRAL RECOGNITION - SYNTHESIS OF THE PURE DIASTEREOISOMERS OF THE BRIDGING BIS(CARBENE) COMPLEX [(FE(C5ME5)(CO)(PME3)MU-2(MU-=C(OME)[CH2]2-C(OME)=)][PF6]2

被引：17

作者：

CRON, S ^{[1
]}

MORVAN, V ^{[1
]}

LAPINTE, C ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM COMPLEXES MET TRANSIT & SYNTH ORGAN LAB,CNRS,URA 415,F-35042 RENNES,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 21期

关键词：

D O I：

10.1039/c39930001611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The C-C bond-forming reaction by direct coupling of two chiral 17-electron metal vinyl units [Fe(C5Me5)(CO)(PMe3)(C(OMe)=CH2)].+ affords the mu-bis(carbene) dimetallic complex [{Fe(C5Me5)(CO)(PMe3)}2{mu-C(OMe)[CH2]2-C(OMe)}][PF6]2 5 with chiral recognition (major: minor = 2:1); the two diastereoisomers are isolated in a pure form.

引用

页码：1611 / 1612

页数：2

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