Reactivities of neutral and cationic organopalladium complexes

被引：28

作者：

Kayaki, Y ^{[1
]}

Shimizu, I ^{[1
]}

Yamamoto, A ^{[1
]}

机构：

[1] WASEDA UNIV, SCH SCI & ENGN, DEPT APPL CHEM, SHINJUKU KU, TOKYO 169, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 12期

关键词：

D O I：

10.1246/cl.1995.1089

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel, neutral and cationic monoorganopalladium complexes containing the methyl ligand as well as ethyl ligands having polar substituents have been prepared and their reactivities toward CO insertions have been compared, The results indicate that ready availability of CO coordination site in the complexes is the most important factor in determining the reactivities of the monoorganopalladium complexes toward CO insertion.

引用

收藏

页码：1089 / 1090

页数：2

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