ZINC-COMPLEXES OF THE N,N,S LIGAND BIS(PYRAZOLYL)(THIENYL)METHANE

被引：20

作者：

ALSFASSER, R ^{[1
]}

VAHRENKAMP, H ^{[1
]}

机构：

[1] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,ALBERTSTR 21,D-79104 FREIBURG,GERMANY

来源：

INORGANICA CHIMICA ACTA | 1993年 / 209卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)84974-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The recently described ligand bis(pyrazol-1-yl)(thien-2-yl)methane (L3) was reacted with zinc halides with the aim of obtaining complexes with a tetrahedral Zn(N,N,S)Hal coordination. Molecular compounds L3ZnHal2 (Hal=Cl, Br, I) were obtained. A structure determination of the bromide complex showed it to be tetrahedral with two bromine and two pyrazole N ligand atoms. The thiophene sulfur was found to be non-coordinating.

引用

页码：19 / 22

页数：4

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