THE USE OF THIOCARBONYL COMPOUNDS IN CARBON CARBON BOND FORMING REACTIONS

被引：147

作者：

METZNER, P

机构：

[1] Lab. Chimie des Composes Thio-Organ., ISMRA, F-14050 Caen

来源：

SYNTHESIS-STUTTGART | 1992年 / 12期

关键词：

D O I：

10.1055/s-1992-26330

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The behavior of thioaldehydes, thioketones, thiono esters (O-alkyl thioates) and dithio esters (S-alkyl dithioates) has been reviewed. Specific properties of thiocarbonyl compounds have been shown: Michael addition reaction of enethiolates, thiophilic addition of nucleophiles, easy thio-Claisen rearrangement, [4 + 2] cycloaddition with dienes and rich dipolarophile chemistry.

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页码：1185 / 1199

页数：15

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