HEXAKIS(ALKYLTHIO)-SUBSTITUTED UNSYMMETRICAL PHTHALOCYANINES

被引：68

作者：

DABAK, S

GUL, A

BEKAROGLU, O

机构：

[1] TECH UNIV ISTANBUL, DEPT CHEM, ISTANBUL, TURKEY

[2] TUBITAK, MARMARA RES CTR, DEPT CHEM, 41470 GEBZE, TURKEY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1994年 / 127卷 / 10期

关键词：

PHTHALOCYANINES; UNSYMMETRICAL; SOLUBLE; BORON COMPLEX; PHTHALONITRILE DERIVATIVES;

D O I：

10.1002/cber.19941271025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclotrimerization of 4,5-bis(hexylthio)phthalodinitrile (1) in 1-chloronaphthalene in the presence of BCl3 leads to the subphthalocyanine 4. Unsymmetrical phthalocyanines (5, 6) with six alkylthio substituents on three of the benzenoid units are synthesized by the reaction of 4 with an diminoisoindoline derivative (R' = H or NO2). These extremely soluble compounds are characterized by IR, H-1- and C-13-NMR as well as UV/Vis spectra.

引用

页码：2009 / 2012

页数：4

共 28 条

[1] SYNTHESIS AND CHARACTERIZATION OF METAL-FREE AND METAL DERIVATIVES OF A NOVEL SOLUBLE CROWN-ETHER-CONTAINING PHTHALOCYANINE [J].