A NEW, GENERAL CYCLOPENTENONE SYNTHESIS

被引:39
作者
CECCHERELLI, P
CURINI, M
MARCOTULLIO, MC
ROSATI, O
WENKERT, E
机构
[1] UNIV PERUGIA,FAC FARM,IST CHIM ORGAN,I-06100 PERUGIA,ITALY
[2] UNIV CALIF SAN DIEGO,DEPT CHEM D-006,LA JOLLA,CA 92093
关键词
D O I
10.1021/jo00288a052
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new synthesis of cyclopentenones, involving an Rh(II)-catalyzed, intramolecular carbon-hydrogen insertion of diazomethyl ketones derived from α,β-unsaturated acids, is described. © 1990, American Chemical Society. All rights reserved.
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页码:311 / 315
页数:5
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