A CONCISE SYNTHESIS OF THE BRASSINOLIDE SIDE-CHAIN

被引：23

作者：

BACK, TG

BLAZECKA, PG

KRISHNA, MV

机构：

[1] Department of Chemistry, University of Calgary, Calgary

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 37期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0040-4039(00)93468-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The brassinolide side chain was produced by the addition of (E)-propenyllithium to the C-22 aldehyde 2, followed by Sharpless epoxidation and epoxide opening with 1-Pr2CuCNLi2.

引用

页码：4817 / 4818

页数：2

共 15 条

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[12] EPOXIDATIONS WITH M-CHLOROPERBENZOIC ACID [J].

SCHWARTZ, NN ;

BLUMBERGER, JH .

JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (07) :1976-&

[13]

Sharpless K. B., 1979, ALDRICHIM ACTA, V12, P63

[14] THERMAL DECOMPOSITION OF VINYLIC COPPER(I) AND SILVER(I) ORGANOMETALLIC COMPOUNDS [J].

WHITESIDES, GM ;

CASEY, CP ;

KRIEGER, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (06) :1379-+

[15]

ZHOU WS, 1990, TETRAHEDRON, V46, P3173

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