IR AND NMR-STUDIES ON ZIRCONOCENE DICHLORIDE METHYLALUMOXANE SYSTEMS-CATALYSTS FOR OLEFIN POLYMERIZATION

被引：55

作者：

NEKHAEVA, LA

BONDARENKO, GN

RYKOV, SV

NEKHAEV, AI

KRENTSEL, BA

MARIN, VP

VYSHINSKAYA, LI

KHRAPOVA, IM

POLONSKII, AV

KORNEEV, NN

机构：

[1] NI LOBACHEVSKII STATE UNIV,INST CHEM,GORKI 603600,USSR

[2] MOSCOW ORGANOELEMENT CPDS RES INST,MOSCOW 111123,RUSSIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 406卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)83180-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction of zirconocene dichloride derivatives with methylalumoxane (MAO) was studied in toluene medium under argon and ethylene atmospheres by IR, H-1, C-13, Al-27 and Si-29 NMR spectroscopy. Data relating to polymerization of ethylene on these catalysts are given.

引用

页码：139 / 146

页数：8

共 36 条

[11]

HERBERHOLD M, 1972, METAL PI COMPLEXES, V5

[12]

HERRMANN WA, 1989, ANGEW CHEM, V101, P1536

[13] STERIC INFLUENCE OF THE TRIMETHYLSILYL GROUP IN ORGANIC-REACTIONS [J].