Asymmetric Simmons-Smith cyclopropanation of E-allylic alcohols using 1,1'-bi-2-naphthol-3,3'-dicarboxamide as a chiral auxiliary

被引：62

作者：

Kitajima, H ^{[1
]}

Aoki, Y ^{[1
]}

Ito, K ^{[1
]}

Katsuki, T ^{[1
]}

机构：

[1] KYUSHU UNIV 33, FAC SCI, DEPT CHEM, HIGASHI KU, FUKUOKA 81281, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 12期

关键词：

D O I：

10.1246/cl.1995.1113

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N,N,N'N'-Tetraethyl- 1, 1'-bi-2-naphthol-3,3'-dicarboxamide (1b) was found to be an effective chiral auxiliary for asymmetric Simmons-Smith cyclopropanation and high enantioselectivity greater than 85% ee was achieved in the reaction of E-allylic alcohols.

引用

页码：1113 / 1114

页数：2

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