NEW CHIRAL PHOSPHINE-LIGANDS CONTAINING (ETA-6-ARENE)CHROMIUM AND CATALYTIC ASYMMETRIC CROSS-COUPLING REACTIONS

被引：53

作者：

UEMURA, M

MIYAKE, R

NISHIMURA, H

MATSUMOTO, Y

HAYASHI, T

机构：

[1] HOKKAIDO UNIV,CATALYSIS RES CTR,SAPPORO,HOKKAIDO 060,JAPAN

[2] HOKKAIDO UNIV,GRAD SCH PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 02期

关键词：

D O I：

10.1016/S0957-4166(00)80193-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New chiral monophosphine ligands 2-4 containing (eta(6)-arene)chromium were prepared via the stereoselective ortho-lithiation of ((R)-N,N-dimethyl-1-phenylethylamine)-Cr(CO)3 (1). Asymmetric cross-coupling of 1-phenylethylmagnesium or -zinc reagent with vinyl bromides in the presence of palladium or nickel catalysts complexed with the chiral (eta(6)-arene)chromium ligands gave the coupling products of up to 61% ee.

引用

收藏

页码：213 / 216

页数：4

相关论文

共 29 条

[1]

[Anonymous], ADV MET ORG CHEM

[2] THE DIASTEREOSELECTIVE FUNCTIONALIZATION OF ARENE TRICARBONYLCHROMIUM COMPLEXES CONTAINING A BENZYLIC HETEROATOM SUBSTITUENT [J].

BLAGG, J ;

DAVIES, SG ;

GOODFELLOW, CL ;

SUTTON, KH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1987, (08) :1805-1811

[3] SYNTHETIC APPLICATIONS OF ENANTIOSELECTIVE ORGANOTRANSITION-METAL-MEDIATED REACTIONS [J].

BLYSTONE, SL .

CHEMICAL REVIEWS, 1989, 89 (08) :1663-1679

[4]

BRUNNER H, 1988, SYNTHESIS-STUTTGART, P645

[5]

BRUNNER H, 1988, TOP STEREOCHEM, V18, P129

[6] ENANTIOSELECTIVE HOMOGENEOUS CATALYSIS INVOLVING TRANSITION-METAL ALLYL INTERMEDIATES [J].

CONSIGLIO, G ;

WAYMOUTH, RM .

CHEMICAL REVIEWS, 1989, 89 (01) :257-276

[7] ENANTIOSELECTIVE CROSS-COUPLING OF VINYL-ELECTROPHILES, ARYL-ELECTROPHILES AND ALLYL-ELECTROPHILES CATALYZED BY NICKEL-COMPLEXES CONTAINING (R,R)-1,2-CYCLOPENTANEDIYLBIS(DIPHENYLPHOSPHINE) AND RELATED LIGANDS [J].

CONSIGLIO, G ;

INDOLESE, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 417 (1-2) :C36-C40

[8] TRANSITION-METAL CATALYZED ASYMMETRIC CROSS COUPLING REACTIONS - NEW LIGANDS AND THE EFFECTS OF ADDED SALTS - CRYSTAL-STRUCTURES OF [PH2PCH2CH((CH2)3SME)NME2].PDCL2 AND [PH2PCH2CH((CH2)2SME)NME2].PDCL2 [J].

CROSS, G ;

VRIESEMA, BK ;

BOVEN, G ;

KELLOGG, RM ;

VANBOLHUIS, F .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 370 (1-3) :357-381

[9]

Davies SG, 1991, ADV METAL ORGANIC CH, V2, P1

[10] ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE METAL-COMPLEXES [J].

HAYASHI, T .

PURE AND APPLIED CHEMISTRY, 1988, 60 (01) :7-12