SYNTHESIS AND STRUCTURE OF THE FIRST SULFUR-BRIDGED [1]FERROCENOPHANE

被引：75

作者：

PUDELSKI, JK ^{[1
]}

GATES, DP ^{[1
]}

RULKENS, R ^{[1
]}

LOUGH, AJ ^{[1
]}

MANNERS, I ^{[1
]}

机构：

[1] UNIV TORONTO,DEPT CHEM,TORONTO,ON M5S 1A1,CANADA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 13-14期

关键词：

METALLOCENOPHANES; POLYMERIZATIONS; POLY(METALLOCENE)S; RING-OPENING POLYMERIZATION; SANDWICH COMPLEXES;

D O I：

10.1002/anie.199515061

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A sulfur atom is the smallest bridging element yet incorporated into a [1]ferrocenophane. This is demonstrated by the synthesis of the purple, crystalline [1]ferrocenophane 1 (structure depicted on the right). The 31.05(10)° tilt angle between the planes of the cyclopentadienyl rings is the largest for any iron group [n]metallocenophane. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：1506 / 1508

页数：3

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