AN UNUSUAL REDUCTION OF ETHYLENE OCCURRING DURING THE THERMAL-DECOMPOSITION OF ALKALIDES AND ELECTRIDES

被引：36

作者：

CAULIEZ, PM

JACKSON, JE

DYE, JL

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

[2] MICHIGAN STATE UNIV,CTR FUNDAMENTAL MAT RES,E LANSING,MI 48824

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 38期

关键词：

D O I：

10.1016/S0040-4039(00)93422-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkalides and electrides thermally decompose by a reductive elimination process leading to the formation of ethylene and a ring opened complexant which has lost an ethylenic unit. Surprisingly, gas phase nmr also shows the formation of ethane and butane. We postulate that these compounds arise from a reduction of the first-formed ethylene by the alkalide or electride.

引用

页码：5039 / 5042

页数：4

共 13 条

[11] 1ST OBSERVATION OF ALKENE RADICAL-ANIONS BY ELECTRON-SPIN-RESONANCE SPECTROSCOPY - ELECTRON AND HOLE TRAPPING IN HEXENE NORMAL-HEXANE MIXED-CRYSTALS IRRADIATED AT 4.2 K
MUTO, H
NUNOME, K
MATSUURA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (05) : 1840 - 1841
[12] DISSOLVING METAL REDUCTION WITH CROWN ETHER - REDUCTIVE REMOVAL OF ISOCYANO GROUPS
OHSAWA, T
MITSUDA, N
NEZU, J
OISHI, T
[J]. TETRAHEDRON LETTERS, 1989, 30 (07) : 845 - 846
[13] NANOSCALE METAL PARTICLES BY HOMOGENEOUS REDUCTION WITH ALKALIDES OR ELECTRIDES
TSAI, KL
DYE, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (05) : 1650 - 1652

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