XEOF5-, AN ANION WITH PENTAGONAL-PYRAMIDAL STRUCTURE

被引：22

作者：

ELLERN, A ^{[1
]}

SEPPELT, K ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST ANORGAN & ANALYT CHEM,D-14195 BERLIN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 15期

关键词：

FLUORINE COMPOUNDS; XENON COMPOUNDS;

D O I：

10.1002/anie.199515861

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Only minimally distorted by interionic forces in the crystal, the ion XeOF 5− (picture on the right, bond lengths in pm) can be crystallized as NO+XeOF 5−. The xenon atom is situated only slightly above the plane through the fluorine atoms, and the doubly bonded oxygen atom occupies the apical position of the pentagonal pyramid. NO+XeOF 5− is formed directly by treatment of NOF with an equimolar amount of XeOF4 and crystallizes spontaneously from the liquid phase. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1586 / 1587

页数：2

共 29 条

[1] STRUCTURE OF CUBIC PHASE OF XENON HEXAFLUORIDE AT 193 DEGREES K [J].

BURBANK, RD ;

JONES, GR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (01) :43-48

[2] ALKALI-METAL FLUORIDE-IODINE PETAFLUORIDE ADDUCTS [J].

CHRISTE, KO .

INORGANIC CHEMISTRY, 1972, 11 (06) :1215-&

[3] ON THE STRUCTURE OF THE [XEOF5](-) ANION AND OF HEPTACOORDINATED COMPLEX FLUORIDES CONTAINING ONE OR 2 HIGHLY REPULSIVE LIGANDS OR STERICALLY ACTIVE FREE VALENCE ELECTRON PAIRS [J].

CHRISTE, KO ;

DIXON, DA ;

SANDERS, JCP ;

SCHROBILGEN, GJ ;

TSAI, SS ;

WILSON, WW .

INORGANIC CHEMISTRY, 1995, 34 (07) :1868-1874

[4] FLUORIDE CRYSTAL-STRUCTURES .24. TETRAFLUOROIODINE(V) MU-FLUORO-BIS[PENTAFLUOROANTIMONATE(V)] [J].

EDWARDS, AJ ;

TAYLOR, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (21) :2174-2177

[5] XEF3+, XEOF3+, AND XEO2F+ CATIONS - PREPARATION AND CHARACTERIZATION BY FLUORINE-19 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY [J].

GILLESPIE, RJ ;

SCHROBILGEN, GJ .

INORGANIC CHEMISTRY, 1974, 13 (10) :2370-2374

[6] CRYSTAL-STRUCTURE OF CS+[(XEOF4)3F] AND VIBRATIONAL STUDY OF THE O-18-ENRICHED [XEOF5] AND [(XEOF4)3F] ANIONS [J].

HOLLOWAY, JH ;

KAUCIC, V ;

MARTINROVET, D ;

RUSSELL, DR ;

SCHROBILGEN, GJ ;

SELIG, H .

INORGANIC CHEMISTRY, 1985, 24 (05) :678-683

[7] STRUCTURE ANALYSES COMBINING ELECTRON DIFFRACTION AND MICROWAVE DATA .1. STUDY OF XEOF4 [J].

JACOB, EJ ;

THOMPSON, HB ;

BARTELL, LS .

JOURNAL OF MOLECULAR STRUCTURE, 1971, 8 (04) :383-&

[8]

Mahjoub A. R., 1991, ANGEW CHEM, V103, P309

[9]

Mahjoub A. R., 1989, ANGEW CHEM, V101, P1528, DOI DOI 10.1002/ange.19891011108

[10] THE STRUCTURE OF BRF-6(-) AND RELATED-COMPOUNDS [J].

MAHJOUB, AR ;

HOSER, A ;

FUCHS, J ;

SEPPELT, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (11) :1526-1527

← 1 2 3 →