THE SYNTHESIS OF TRIS(PERFLUOROALKYL)-PHOSPHANES

被引：24

作者：

KAMPA, JJ ^{[1
]}

NAIL, JW ^{[1
]}

LAGOW, RJ ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 11期

关键词：

FLUORINE COMPOUNDS; MASS SPECTROMETRY; NMR SPECTROSCOPY; PHOSPHORUS COMPOUNDS;

D O I：

10.1002/anie.199512411

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Symmetric, unsymmetric, and bridged perfluorinated trialkylphosphanes and diphosphanes are accessible for the first time by the general method outlined in this communication. In the synthesis, trialkylphosphanes are treated with elemental fluorine, and the resulting difluorotris(perfluoroalkyl)phosphoranes reduced to the desired perfluorinated phosphanes with tris(trimethylsilyl)phosphane. Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1241 / 1244

页数：4