DIRECT CATALYTIC CONVERSION OF METHANE

被引：30

作者：

POIRIER, MG ^{[1
]}

SANGER, AR ^{[1
]}

SMITH, KJ ^{[1
]}

机构：

[1] ALBERTA RES COUNCIL,DEVON T0C 1E0,ALBERTA,CANADA

来源：

CANADIAN JOURNAL OF CHEMICAL ENGINEERING | 1991年 / 69卷 / 05期

关键词：

METHANE; DIRECT CATALYTIC CONVERSION OF METHANE; OXIDATIVE COUPLING; PARTIAL OXIDATION;

D O I：

10.1002/cjce.5450690502

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Processes are being developed for the direct catalytic oxidative conversion of methane to higher hydrocarbons and oxygenates. The role of the catalyst in generating methyl radicals is established, and subsequent gas-phase reactions are well understood. However, the role of several catalyst surface species remains a subject of interest. Application of present process technology using the most promising catalysts shows that direct methane conversion is not yet competitive with conventional processes. Increased yields of desirable products using new process configurations are required to obtain an economically viable process.

引用

页码：1027 / 1035

页数：9

共 91 条

[41] Jones C. A., 1985, U. S. Patent, Patent No. [4,554,395, 4554395]
[42] Jones C. A., 1986, U. S. Patent, Patent No. [4,567,307, 4567307]
[43] THE OXIDATIVE CONVERSION OF METHANE TO HIGHER HYDROCARBONS OVER ALKALI-PROMOTED MN/SIO2
JONES, CA
LEONARD, JJ
SOFRANKO, JA
[J]. JOURNAL OF CATALYSIS, 1987, 103 (02) : 311 - 319
[44] JONES CA, 1985, Patent No. 804
[45] JONES CA, 1987, Patent No. 4665260
[46] JONES CA, 1985, Patent No. 4499322
[47] Jones CA, 1984, US Patent, Patent No. [4444984 A ., 4444984]
[48] JONES CA, 1985, Patent No. 4547807
[49] LOW-TEMPERATURE, PALLADIUM(II)-CATALYZED, SOLUTION-PHASE OXIDATION OF METHANE TO A METHANOL DERIVATIVE
KAO, LC
HUTSON, AC
SEN, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (02) : 700 - 701
[50] KASZTELAN S, 1989, J CATAL, V112, P82

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