STEP-WISE NUCLEOPHILIC-SUBSTITUTION OF BIS(CYCLOPENTADIENYL)TIN(II) - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [(SN(ETA(3)-C5H5)[MU-N=C(NME(2))(2)])(2)] AND [(SN[S(CH2)(3)SC(R)]-[MU-N=C(NME(2))(2)])(2)] (R=H OR SIME(3))

被引：18

作者：

EDWARDS, AJ ^{[1
]}

PAVER, MA ^{[1
]}

RAITHBY, PR ^{[1
]}

RENNIE, MA ^{[1
]}

RUSSELL, CA ^{[1
]}

WRIGHT, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 10期

关键词：

D O I：

10.1039/dt9950001587

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nucleophilic substitution of Sn(C5H5)(2) with LiN=C(NMe(2))(2) led to the monosubstitution of only one C5H5 ligand yielding dimeric [{Sn(eta(3)-C5H5)[mu-N=C(NMe(2))(2)]}(2)] in which the remaining C5H5 group can be further substituted by reactions with lithiated 1,3-dithianes to give the dimeric mixed-ligand imino-1,3-dithiane complexes [{Sn[S(CH2)(3)SC(R)][mu-N=C(NMe(2))(2)]}(2)] (R = H or SiMe(3)).

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页码：1587 / 1591

页数：5

相关论文

共 33 条

[1] THE OBSERVATION OF A PB-LI BOND - SYNTHESIS, STRUCTURE AND MODEL MOLECULAR-ORBITAL (MO) CALCULATIONS ON THE MONOMERIC PH3PB-LI.(PMDETA) COMPLEX [PMDETA=(ME2NCH2CH2)2NME] [J].

ARMSTRONG, DR ;

DAVIDSON, MG ;

MONCRIEFF, D ;

STALKE, D ;

WRIGHT, DS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (19) :1413-1415

[2] THE BIS(CYCLOPENTADIENYL)THALLATE(I) ANION ISOELECTRONIC WITH STANNOCENE [J].

ARMSTRONG, DR ;

HERBSTIRMER, R ;

KUHN, A ;

MONCRIEFF, D ;

PAVER, MA ;

RUSSELL, CA ;

STALKE, D ;

STEINER, A ;

WRIGHT, DS .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1993, 32 (12) :1774-1776

[3]

ARMSTRONG DR, 1993, ANGEW CHEM, V105, P1807

[4] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[5] STRUCTURE AND BONDING OF THE TRIS(DIPHENYLMETHYLENEAMINO)ALUMINIUM DIMER [AL(NCPH2)3]2 - RELATIVE STRENGTHS OF BRIDGING AND TERMINAL AL-X BONDS IN SYSTEMS X2AL(MU-2-X)2ALX2 [J].

BRYAN, SJ ;

CLEGG, W ;

SNAITH, R ;

WADE, K ;

WONG, EH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (16) :1223-1224

[6] CRYSTALLINE BINUCLEAR CIS-CHLOROTIN(II) AND TRANS-CHLOROTIN(II) AMIDES [SN(MU-CL)(NR2)]2, THE CIS-1A REVERSIBLE TRANS-1B ISOMERIZATION FOR [NR2 = NCME2(CH2)3CME2], AND THE X-RAY STRUCTURES OF 1A AND OF TRANS-[SN(MU-CL)(N(SIME3)2)]2 [J].

CHORLEY, RW ;

HITCHOCK, PB ;

JOLLY, BS ;

LAPPERT, MF ;

LAWLESS, GA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (18) :1302-1303

[7] AZOMETHINE DERIVATIVES .20. CRYSTAL AND MOLECULAR-STRUCTURES OF THE LITHIOKETIMINE [(LI(N=CBUT2))6] AND LITHIOGUANIDINE [(LI[N=C(NME2)2])6] - ELECTRON-DEFICIENT BRIDGING OF LI-3 TRIANGLES BY METHYLENEAMINO-NITROGEN ATOMS [J].

CLEGG, W ;

SNAITH, R ;

SHEARER, HMM ;

WADE, K ;

WHITEHEAD, G .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (07) :1309-1317

[8] [(ETA-5-CP)2SN(MU-ETA-5-CP)NA.PMDETA], A COMPOUND WITH A TRIGONAL-PLANAR PADDLE WHEEL TRIORGANOSTANNATE ION [J].

DAVIDSON, MG ;

STALKE, D ;

WRIGHT, DS .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1992, 31 (09) :1226-1227

[9] SUB-VALENT GROUP 4B METAL ALKYLS AND AMIDES .1. SYNTHESIS AND PHYSICAL-PROPERTIES OF KINETICALLY STABLE BIS[BIS(TRIMETHYSILYL)METHYL]-GERMANIUM(II), BIS[BIS(TRIMETHYSILYL)METHYL]-TIN(II), AND BIS[BIS(TRIMETHSILYL)METHYL]-LEAD(II) [J].

DAVIDSON, PJ ;

HARRIS, DH ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (21) :2268-2274

[10] 2 TRIORGANOSTANNATE COMPLEXES SYNTHESIZED FROM BIS(CYCLOPENTADIENYL)TIN(II) - STRUCTURAL VARIATION BETWEEN [MG(THF)6]2+2[SN(ETA-3-C5H5)3]- AND [LI(THF)4]+[SN(C13H9)3]- (THF = TETRAHYDROFURAN, C13H9 = FLUORENYL) [J].

EDWARDS, AJ ;

PAVER, MA ;

RAITHBY, PR ;

RUSSELL, CA ;

STALKE, D ;

STEINER, A ;

WRIGHT, DS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (09) :1465-1466

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