CHARACTERIZATION OF CARBON-SUPPORTED PT-SN BIMETALLIC CATALYSTS FOR THE ELECTROCHEMICAL OXIDATION OF METHANOL

被引:18
作者
GOKAGAC, G
KENNEDY, BJ
CASHION, JD
BROWN, LJ
机构
[1] UNIV SYDNEY,DEPT INORGAN CHEM,SYDNEY,NSW 2006,AUSTRALIA
[2] MONASH UNIV,DEPT PHYS,CLAYTON,VIC 3168,AUSTRALIA
来源
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1993年 / 89卷 / 01期
关键词
D O I
10.1039/ft9938900151
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carbon-supported platinum oxide-tin oxide samples have been studied as electrocatalysts for methanol oxidation. The Teflon-bonded electrodes are found to be poor electrocatalysts. X-Ray photoelectron and Mossbauer spectroscopy, together with electron microscopy, have been used to determine the nature of the bimetallic crystallites. Differences in the activity of various Pt-Sn-containing electrodes for methanol oxidation are discussed.
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页码:151 / 157
页数:7
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