Cyclization of diols with ammonia over CuO-ZnO-Al2O3 catalyst in the presence of H-2

被引：2

作者：

Shuikin, AN ^{[1
]}

Kliger, GA ^{[1
]}

Zaikin, VG ^{[1
]}

Glebov, LS ^{[1
]}

机构：

[1] IM GUBKIN STATE ACAD OIL & GAS,MOSCOW 117917,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1995年 / 44卷 / 10期

关键词：

diols; ammonia; cyclization; heterocyclic amines; copper-containing catalyst;

D O I：

10.1007/BF00707239

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclization of diols with ammonia in an Hz atmosphere over an industrial CuO-ZnO-Al2O3 catalyst for the synthesis of methanol (SNM-1) gives nitrogen-containing five-, six-, or seven-membered heterocyclic compounds. The yields of cyclic amines in the 180-230 degrees C temperature range are 46 to 97 %.

引用

页码：1966 / 1967

页数：2

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