PHOTOIONIZATION AND PHOTODISSOCIATION OF NITRIC-OXIDE IN THE RANGE 9-35-EV

被引：49

作者：

ERMAN, P

KARAWAJCZYK, A

RACHLEWKALINE, E

STROMHOLM, C

机构：

[1] Department of Physics I, Royal Institute of Technology

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 102卷 / 08期

关键词：

D O I：

10.1063/1.468616

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photoionization and photodissociation of NO has been studied using 9-35 eV synchrotron light and detection of fluorescence as well as of mass selected NO+, N+, O+, and O- ions. Rydberg series converging to all known states in NO+ below 24 eV have been analyzed and classified and several of them are found to be predissociated by various NO+ states as well as by NO ion pair states. The complex structure in the 950-1200 Å excitation region is suggested to originate from interaction between a "new" NO valence state at T0=77 470 cm-1 and high vibrational levels of Rydberg series converging to the NO+ ground state. © 1995 American Institute of Physics.

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页码：3064 / 3076

页数：13

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