REGIOSELECTIVITY CONTROL IN THE PALLADIUM-CATALYZED COPOLYMERIZATION OF PROPYLENE WITH CARBON-MONOXIDE

被引：83

作者：

BATISTINI, A ^{[1
]}

CONSIGLIO, G ^{[1
]}

SUTER, UW ^{[1
]}

机构：

[1] SWISS FED INST TECHNOL,INST POLYMERE,CH-8092 ZURICH,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 03期

关键词：

D O I：

10.1002/anie.199203031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With 1,3-propanediylbis(diisopropylphosphine) as ligand L in [Pd(CF3CO2)2L] precatalysts, the strict alternating copolymerization of propylene with carbon monoxide can be carried out with complete regioselectivity and good stereoselectivity. Thus the first synthesis of a regular poly(1-oxo-2-methyltrimethylene) has been achieved. The possible configurations in this polymer are shown below.

引用

页码：303 / 305

页数：3

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