BIS(PHOSPHINE)GOLD(I) DERIVATIVES WITH 7,7',8,8'-TETRACYANOQUINODIMETHANE X-RAY STRUCTURE OF [AU(PPH3)2]TCNQ

被引：4

作者：

ALONSO, PJ ^{[1
]}

CERRADA, E ^{[1
]}

GARIN, J ^{[1
]}

GIMENO, MC ^{[1
]}

LAGUNA, A ^{[1
]}

LAGUNA, M ^{[1
]}

JONES, PG ^{[1
]}

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,W-3300 BRAUNSCHWEIG,GERMANY

来源：

SYNTHETIC METALS | 1993年 / 56卷 / 01期

关键词：

GOLD; TETRACYANOQUINODIMETHANE; PHOSPHINE; CHARGE-TRANSFER SALTS;

D O I：

10.1016/0379-6779(93)90323-O

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The complexes [Au(PR3)2]ClO4 (PR3 = PPh3, PPh2Me, P(p-MeC6H4)3 or P(p-MeOC6H4)3) react with LiTCNQ to give Au(PR3)2TCNQ. The same results arc obtained if free TCNQ is present in the reaction mixture. The structure of [Au(PPh3)2TCNQ] has been established by single-crystal X-ray diffraction studies and shows a short Au ... N contact of 3.21 angstrom.

引用

页码：1772 / 1776

页数：5

共 19 条

[1] SYNTHESIS AND CRYSTAL-STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)GOLD TRICYANOMETHANIDE, [(PPH3)2AU]+ [C(CN)3]- [J].

BAUKOVA, TV ;

KRAVTSOV, DN ;

KUZMINA, LG ;

DVORTSOVA, NV ;

PORAYKOSHITS, MA ;

PEREVALOVA, EG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 372 (03) :465-471

[2]

BAUKOVA TV, 1991, MENDELEEV COMMUN, P22

[3] NOVEL ORGANOMETALLIC CHARGE-TRANSFER SALTS DERIVED FROM ELECTRON-RICH DIRUTHENIUM SPECIES AND THE ELECTRON-ACCEPTOR LIGANDS 7,7,8,8-TETRACYANO-PARA-QUINODIMETHANE AND TETRACYANOETHYLENE AND CONTAINING THE RADICAL-ANIONS OF THESE LIGANDS IN BOTH THE INNER AND THE OUTER COORDINATION SPHERES [J].

BELL, SE ;

FIELD, JS ;

HAINES, RJ ;

SUNDERMEYER, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 427 (01) :C1-C5

[4]

Coppens P., 1978, ANN NY ACAD SCI, V313, P244

[5] BOND LENGTHS AND CHARGE-TRANSFER IN TETRACYANOQUINODIMETHANE SALTS [J].

FLANDROIS, S ;

CHASSEAU, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (SEP15) :2744-2750

[6] USE OF CONDUCTIVITY MEASUREMENTS IN ORGANIC SOLVENTS FOR CHARACTERISATION OF COORDINATION COMPOUNDS [J].

GEARY, WJ .

COORDINATION CHEMISTRY REVIEWS, 1971, 7 (01) :81-&

[7] ORGANOMETALLIC SOLID-STATE CHEMISTRY [J].

GREEN, MLH ;

QIN, JG ;

OHARE, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 358 (1-3) :375-388

[8]

HAEKSTRA A, 1972, ACTA CRYSTALLOGR B, V28, P14

[9] STRUCTURE OF THE ORGANIC SUPERCONDUCTOR (DMET)2AUCL2 [J].

ISHIKAWA, Y ;

SAITO, K ;

KIKUCHI, K ;

IKEMOTO, I ;

KOBAYASHI, K ;

ANZAI, H .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 :1652-1655

[10]

JONES PG, 1980, ACTA CRYSTALLOGR B, V36, P3107

← 1 2 →