ALKYLCOBALT CARBONYLS .10. CO ACTIVATION AND PHASE-TRANSFER-ACTIVE COORDINATION SITES IN ORGANOCOBALT CARBONYLS - MECHANISM OF THE REACTION OF BENZYL HALIDES AND TETRACARBONYLCOBALTATE(-I)

被引:23
作者
HAASZ, F
BARTIK, T
GALAMB, V
PALYI, G
机构
[1] HUNGARIAN ACAD SCI, PETROCHEM RES GRP, H-8201 VESZPREM, HUNGARY
[2] ALKALOIDA CHEM CO, H-4440 TISZAVASVARI, HUNGARY
[3] EOTVOS LORAND UNIV, INST GEN & INORGAN CHEM, H-1088 BUDAPEST, HUNGARY
关键词
D O I
10.1021/om00160a026
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
(4’-Halomethyl-1’,2’-benzo)-15-crown-5 (RX, 1; X = Cl (a), I (b)) compounds were reacted with Na-[Co(CO)4] (2). The corresponding η1-RC(O)Co(CO)4 (5), η1-RCo(CO)4 (6), and η3-RCo(CO)3 (7) derivatives were obtained through intermediates [(η5-RX)Na] [Co(CO)4] (3) and [(η5-Na+)RC(O)Co(CO)3(X-)] (4). The reactions leading to 7 from 1 were found to be reversible. Derivatives of 4 and 5 were prepared by monosubstitution with PPh3, giving 8 and 9, respectively. The reversibility of the reaction of PhCH2Cl with 2 was also demonstrated. © 1990, American Chemical Society. All rights reserved.
引用
收藏
页码:2773 / 2779
页数:7
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