SYNTHESIS OF ETHENYL(PHENYL)IODONIUM TRIFLATE, [H2C=CHIPH][OSO2CF3], AND ITS APPLICATION AS A PARENT VINYL CATION EQUIVALENT

被引：24

作者：

STANG, P

ULLMANN, J

机构：

[1] Department of Chemistry, University of Utah, Salt Lake City, Utah

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 11期

关键词：

D O I：

10.1002/anie.199114691

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As a reactive, strongly electrophilic vinylating agent the title compound complements the known nucleophilic vinylation reagents. It reacts with catalytic amounts of silver triflate to give the parent vinyl triflate 1 and undergoes oxidative addition reactions with organometallic compounds. Reaction with Vaska's complex, for example, furnishes 2.

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页码：1469 / 1470

页数：2

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