SYNTHESIS OF ETHENYL(PHENYL)IODONIUM TRIFLATE, [H2C=CHIPH][OSO2CF3], AND ITS APPLICATION AS A PARENT VINYL CATION EQUIVALENT

被引:24
作者
STANG, P
ULLMANN, J
机构
[1] Department of Chemistry, University of Utah, Salt Lake City, Utah
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 11期
关键词
D O I
10.1002/anie.199114691
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
As a reactive, strongly electrophilic vinylating agent the title compound complements the known nucleophilic vinylation reagents. It reacts with catalytic amounts of silver triflate to give the parent vinyl triflate 1 and undergoes oxidative addition reactions with organometallic compounds. Reaction with Vaska's complex, for example, furnishes 2.
引用
收藏
页码:1469 / 1470
页数:2
相关论文
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