OPTICALLY-ACTIVE SULFOXIDES BY ENANTIOSPECIFIC REACTIONS OF BROMOVINYL ARYL SULFOXIDES WITH GRIGNARD-REAGENTS

被引：36

作者：

CARDELLICCHIO, C ^{[1
]}

FIANDANESE, V ^{[1
]}

NASO, F ^{[1
]}

SCILIMATI, A ^{[1
]}

机构：

[1] UNIV BARI,DIPARTIMENTO CHIM,CNR,CTR STUDIO METODOL INNOVAT SINTESI ORGAN,VIA AMENDOLA 173,I-70126 BARI,ITALY

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 35期

关键词：

SULFOXIDE; ORGANOMAGNESIUM; HALOALKENES; ENANTIOSPECIFICITY; OXIDATION;

D O I：

10.1016/S0040-4039(00)61207-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optically active bromovinyl aryl sulfoxides were subjected to reactions with phenyl- or alkyl-magnesium compounds, with the production of optically active diaryl or aryl alkyl sulfoxides, with inversion of configuration. The enantiospecificity of the process was found to be 98-100%.

引用

页码：5121 / 5124

页数：4

共 27 条

[1]

Andersen K. K., 1988, CHEM SULPHONES SULPH, p[823, 55]

[2] ASYMMETRIC OXIDATION OF 1,3-DITHIOLANES - A ROUTE TO THE OPTICAL RESOLUTION OF CARBONYL-COMPOUNDS [J].