THE GENERATION OF 2,3-DIHYDRO-2,3-BIS-(METHYLENE)THIOPHENES FROM 4,6-DIHYDROTHIENO[3,4-B]THIOPHENE 5,5-DIOXIDES

被引：38

作者：

CREW, APA

JENKINS, G

STORR, RC

YELLAND, M

机构：

[1] UNIV LIVERPOOL,SCH CHEM,POB 147,LIVERPOOL L69 3BX,ENGLAND

[2] ICI PLC,FINE CHEM MFG ORG,MANCHESTER M9 3DA,LANCS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 10期

关键词：

D O I：

10.1016/S0040-4039(00)88841-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

On heating in sulpholane 4,6-dihydrothieno[3,4-b]thiophene 5,5-dioxides give 2,3-dihydro-2,3-bis(methylene)thiophenes which can be intercepted in Diels-Alder reactions. Sulphur dioxide is a very efficient trap for these thiophene xylylenes giving the cyclic sulphones by cheletropic addition. © 1990.

引用

页码：1491 / 1494

页数：4