MOLECULAR-HYDROGEN COMPLEXES OF THE TRANSITION-METALS .4. PREPARATION AND CHARACTERIZATION OF MO(CO)3(PR3)2(ETA-2-H-2), W(CO)3(PR3)2(ETA-2-H-2) AND EVIDENCE FOR EQUILIBRIUM DISSOCIATION OF THE H-H BOND TO GIVE MH2(CO)3(PR3)2

被引:283
作者
KUBAS, GJ
UNKEFER, CJ
SWANSON, BI
FUKUSHIMA, E
机构
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D O I
10.1021/ja00282a026
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O6 [化学];
学科分类号
0703 ;
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页码:7000 / 7009
页数:10
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共 88 条
[31]   HYDROGENATION OF ORGANIC COMPOUNDS USING HOMOGENEOUS CATALYSTS [J].
HARMON, RE ;
GUPTA, SK ;
BROWN, DJ .
CHEMICAL REVIEWS, 1973, 73 (01) :21-52
[32]   ABINITIO THEORETICAL-STUDIES OF A NOVEL TUNGSTEN DIHYDROGEN COMPLEX [J].
HAY, PJ .
CHEMICAL PHYSICS LETTERS, 1984, 103 (06) :466-469
[33]  
HAY PJ, J AM CHEM SOC
[34]   IDENTIFICATION OF DIASTEREOISOMERIC TETRACARBONYL[ORTHO-PHENYLENEBIS-(METHYLPHENYLARSINE)]MOLYBDENUM COMPLEXES BY MEANS OF H-1 AND C-13 FOURIER NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY [J].
HENRICK, K ;
WILD, SB .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (23) :2500-2505
[35]   ON THE STABILITY OF THE PDH2 MOLECULE [J].
JARQUE, C ;
NOVARO, O ;
RUIZ, ME ;
GARCIAPRIETO, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (12) :3507-3509
[36]  
JEAN Y, J AM CHEM SOC
[37]   BONDING OF ETA-2-SULFUR DIOXIDE - STRUCTURES OF TRICARBONYL(1,10-PHENANTHROLINE)(ETA-2-SULFUR DIOXIDE)MOLYBDENUM(0) AND DICARBONYL(2,2'-BIPYRIDYL)BIS(ETA-2-SULFUR DIOXIDE)MOLYBDENUM(0) [J].
KUBAS, GJ ;
RYAN, RR ;
MCCARTY, V .
INORGANIC CHEMISTRY, 1980, 19 (10) :3003-3007
[38]   MOLECULAR-HYDROGEN COMPLEXES OF THE TRANSITION-METALS .2. EVIDENCE FOR A NEW COMPLEX, MO(CO)(DPPE)2(H2), AND FOR SOLUTION EQUILIBRIUM BETWEEN DIHYDROGEN AND DIHYDRIDE FORMS, M-ETA-2-H2 REVERSIBLE H-M-H, IN W(CO)3(PR3)2(H2) [J].
KUBAS, GJ ;
RYAN, RR ;
WROBLESKI, DA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (06) :1339-1341
[39]   CHARACTERIZATION OF THE 1ST EXAMPLES OF ISOLABLE MOLECULAR-HYDROGEN COMPLEXES, MO(CO)3(PCY3)2(H2), W(CO)3(PCY3)2(H2),MO(CO)3 (PI-PR3)2(H2),W(CO)3(PI-PR3)2(H2) - EVIDENCE FOR A SIDE-ON BONDED H-2 LIGAND [J].
KUBAS, GJ ;
RYAN, RR ;
SWANSON, BI ;
VERGAMINI, PJ ;
WASSERMAN, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (02) :451-452
[40]   ACTIVATION OF H-2 AND SO2 BY MO AND W COMPLEXES - 1ST EXAMPLES OF MOLECULAR-H-2 COMPLEXES, SO2 INSERTION INTO METAL HYDRIDE BONDS, AND HOMOGENEOUS HYDROGENATION OF SO2 [J].
KUBAS, GJ ;
RYAN, RR .
POLYHEDRON, 1986, 5 (1-2) :473-485