Kinetic and theoretical studies of the hydration of carbon suboxide

被引：11

作者：

Allen, AD

McAllister, MA

Tidwell, TT

机构：

[1] UNIV TORONTO,DEPT CHEM,TORONTO,ON M5S 1A1,CANADA

[2] UNIV CALIF LOS ANGELES,DEPT CHEM,LOS ANGELES,CA 90024

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 24期

关键词：

D O I：

10.1039/c39950002547

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydration rates in H2O of carbon suboxide are substantial but less than those of ketene, by factors of 2.5 x 10(3) and 5.2 x 10(4) for the neutral and acid-catalysed reactions, respectively, in qualitative agreement with ab initio calculated stabilities of probable intermediates.

引用

收藏

页码：2547 / 2548

页数：2

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