SYNTHESES OF ACYLOXY CARBENE COMPLEXES M(SNPH(3))(CO)(N)(=C(OCOR)PH)(ETA-C5H5) (M=MO,W, N=2, R=ME M=FE, RU, N=1, R=ME, PH, BU(T)) AND X-RAY CRYSTAL-STRUCTURES OF FE(SNPH(3))(CO)(=C(OCOR)PH)(ETA-C5H5) (R=ME, PH)

被引：11

作者：

ADAMS, H ^{[1
]}

MALONEY, CA ^{[1
]}

MUIR, JE ^{[1
]}

WALTERS, SJ ^{[1
]}

WINTER, MJ ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 15期

关键词：

D O I：

10.1039/c39950001511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [M(SnPh(3))(COPh)(CO)(n)(eta-C5H5)](-) (M = Fe, Ru, n = 1; M = Mo, W, n = 2) with acid chlorides R(1)COCl affords carbenes [M(SnPh(3))(CO)(n){C(OCOR(1))Ph}(eta-C5H5)], which in the case of the iron and ruthenium derivatives are isolable as unusually stable crystalline solids and which react with sources of thiolate to form the new thiocarbene complexes M(SnPh(3))(CO)(n){C(SR(2))Ph}(eta-C5H5).

引用

页码：1511 / 1512

页数：2

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