INTERCOMPARISON OF TUNABLE DIODE-LASER AND GAS FILTER CORRELATION-MEASUREMENTS OF AMBIENT CARBON-MONOXIDE

被引:25
作者
FRIED, A
HENRY, B
PARRISH, DD
CARPENTER, JR
BUHR, MP
机构
[1] NOAA,AERON LAB,BOULDER,CO 80303
[2] UNIV COLORADO,NOAA,COOPERAT INST RES ENVIRONM SCI,BOULDER,CO 80309
来源
ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS | 1991年 / 25卷 / 10期
基金
美国国家科学基金会;
关键词
TROPOSPHERIC CARBON MONOXIDE MEASUREMENTS; CARBON MONOXIDE INTERCOMPARISON; TUNABLE DIODE LASER CO MEASUREMENTS; GAS FILTER CORRELATION CO MEASUREMENTS;
D O I
10.1016/0960-1686(91)90103-E
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
An intercomparison that involved a standards intercomparison, interferant spiking tests and simultaneous ambient measurements was carried out between two CO measurement systems: a tunable diode laser absorption spectrometer (TDLAS) and a gas filter correlation, non-dispersive infrared absorption instrument (GFC). Both the TDLAS and the GFC techniques responded to CO. No major interferences were found for the TDLAS system; tested species included H2O, O3 and OCS. The GFC instrument exhibited no interference from H2O or O3, but only a relatively high upper limit could be placed on the O3 interference. For CO measurements in ambient air at levels from 100 to 1500 ppbv, the results from the two instruments agreed within their combined uncertainties. On average the GFC technique was 6% higher than the TDLAS system, and there was no systematic, constant offset. The precision of the GFC instrument was about 10%, and the precision of the TDLAS system was better than 4%.
引用
收藏
页码:2277 / 2284
页数:8
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