REACTIONS INVOLVING FLUORIDE-ION .40. AMINES AS INITIATORS OF FLUORIDE-ION CATALYZED-REACTIONS

被引：30

作者：

CHAMBERS, RD ^{[1
]}

GRAY, WK ^{[1
]}

KORN, SR ^{[1
]}

机构：

[1] ZENECA SPECIALITIES,HUDDERSFIELD HD2 1FF,W YORKSHIRE,ENGLAND

来源：

TETRAHEDRON | 1995年 / 51卷 / 48期

关键词：

D O I：

10.1016/0040-4020(95)00787-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tetrakis(dimethylamino)ethene (TDAE) and trimethylamine react with anhydrous unsaturated fluorocarbons to produce, 'in situ', powerful fluoride- ion sources. These are used to initiate carbon- carbon bond forming reactions eg, oligomerisation and polyfluoroalkylation, and many of these reactions occur efficiently in the absence of a solvent.

引用

页码：13167 / 13176

页数：10

共 33 条

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