A BUTADIENEDIYL-BRIDGED DIIRON COMPOUND IN 3 OXIDATION LEVELS

被引：52

作者：

ETZENHOUSER, BA

CHEN, Q

SPONSLER, MB

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

[2] SYRACUSE UNIV,WM KECK CTR MOLEC ELECTR,SYRACUSE,NY 13244

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 11期

关键词：

D O I：

10.1021/om00023a019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A conjugated dinuclear iron complex, [CpFe(dppm)](2)(mu-CH=CHCH=CH), has been prepared and oxidized to radical cation and dication. species. The butadienediyl bridge apparently allows for strong electronic coupling between the iron atoms, as determined by cyclic voltammetry, electronic absorption spectroscopy, and an X-ray crystal structure determination on the dication.

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页码：4176 / 4178

页数：3

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