HOMOGENEOUS AQUEOUS OXIDATION OF ORGANIC-MOLECULES BY OXONE(R) AND CATALYSIS BY A WATER-SOLUBLE MANGANESE PORPHYRIN COMPLEX

被引：30

作者：

ZHENG, TC ^{[1
]}

RICHARDSON, DE ^{[1
]}

机构：

[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 06期

关键词：

D O I：

10.1016/0040-4039(94)02420-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Peroxymonosulfate (KHSO5) oxidizes a wide variety of water-soluble organic molecules in aqueous solutions, and the reactions are generally more rapid in phosphate buffer (pH 6-7) than in pure water. A water-soluble porphyrin complex, meso-tetrakis(4-N-methylpyridyl)porphyrinatomanganese(III) chloride, catalyzes epoxidation and hydroxylation under neutral pH conditions.

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页码：833 / 836

页数：4

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