PULSE-RADIOLYSIS STUDIES ON FE(CN)6]4-BRO3-CN-SYSTEM IN ETHYLENE-GLYCOL - WATER SOLUTIONS

被引：4

作者：

SZABOBARDOS, E ^{[1
]}

WOJNAROVITS, L ^{[1
]}

HORVATH, A ^{[1
]}

机构：

[1] HUNGARIAN ACAD SCI,INST ISOTOPES,H-1525 BUDAPEST,HUNGARY

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES | 1991年 / 147卷 / 02期

关键词：

D O I：

10.1007/BF02040369

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Formation of oxidizing and reducing radicals has been studied by pulse radiolysis of [Fe(CN)6]4--BrO3--CN- system in ethylene glycol - water solvent mixture. Oxidizing .BrO2 and BrO radicals formed by electron scavenging with .BrO3- were identified and their reactions were investigated. The reaction of hydroxyl radicals with ethylene glycol leads to formation of reactive radicals with reducing properties and of compounds which reduce slowly in dark the ferricyanide formed in the reaction of .BrO2 radical with ferrocyanide.

引用

页码：215 / 224

页数：10

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