A CONCISE SYNTHESIS OF (+/-)-MONOMORINE-I BY WAY OF A PALLADIUM-CATALYZED REDUCTIVE COUPLING

被引：16

作者：

CASTANO, AM ^{[1
]}

CUERVA, JM ^{[1
]}

ECHAVARREN, AM ^{[1
]}

机构：

[1] UNIV AUTONOMA MADRID,DEPT QUIM ORGAN,E-28049 MADRID,SPAIN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 40期

关键词：

D O I：

10.1016/0040-4039(94)85335-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A seven steps synthesis of the indolizidine alkaloid (+/-)-monomorine I is described starting from 2-methylpiperidine. The key step of the synthesis is a palladium-catalyzed reductive coupling reaction of an acid chloride with a beta-stannanyl enone to give a 1,4-diketone.

引用

页码：7435 / 7438

页数：4

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