SPECTROSCOPIC STUDIES ON THE AVERAGE-VALENCE COPPER SITE [CU-2](3+)

被引：49

作者：

FARRAR, JA

MCKEE, V

ALOBAIDI, AHR

MCGARVEY, JJ

NELSON, J

THOMSON, AJ

机构：

[1] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND

[2] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 06期

关键词：

D O I：

10.1021/ic00110a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The average-valence Cu-2(3+) Site in bis(copper) complexes with three azacryptands has been probed by electronic absorption, resonance Raman (RR), and magnetic circular dichroism (MCD) spectroscopy. The X-ray structure of one of the complexes is presented. RR excitation profiles of low-frequency Cu-Cu and Cu-N modes establish that at least two vibronic transitions contribute to the absorption intensity in the range 700-900 nm, in agreement with the MCD data and indicative of vibronic transitions involving substantial motion of both copper nuclei.

引用

页码：1302 / &

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