CONTROL OF CARBENOID REACTIVITY THROUGH NEIGHBORING GROUP PARTICIPATION

被引：12

作者：

DAVIES, HML ^{[1
]}

MATASI, JJ ^{[1
]}

THORNLEY, C ^{[1
]}

机构：

[1] WAKE FOREST UNIV,DEPT CHEM,WINSTON SALEM,NC 27109

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 40期

关键词：

D O I：

10.1016/0040-4039(95)01484-Y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Product distribution in the rhodium(II) carboxylate catalyzed decomposition of vinyldiazomethanes in the presence of N-(BOC)pyrroles can be controlled through stabilization of the vinylcarbenoid intermediates by neighboring group participation.

引用

页码：7205 / 7208

页数：4

共 17 条

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[7] RHODIUM(II) CATALYZED INTRAMOLECULAR REACTIONS BETWEEN VINYLDIAZOMETHANES AND PYRROLES - NOVEL SYNTHESIS OF FUSED 7-AZABICYCLO[4.2.0]OCTADIENES [J].

DAVIES, HML ;

MATASI, JJ .

TETRAHEDRON LETTERS, 1994, 35 (29) :5209-5212

[8]

DAVIES HML, 1991, COMPREHENSIVE ORGANI, V4, P1031

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